No, Luigi shouldn't be on the list, because luigi's debut game, Super Mario Brothers, Came out late 1985, whereas Mario was in Donkey Kong, which is a pre-1985 title.
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the fact that they're called "Mario Bros" implies that they've both got mario in their names or their professions. Which they haven't.
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According to the movie the names of the "Mario" Brothers are Mario Mario and Luigi Mario, but I dunno if that goes for the original games.